Reaction of N-sulfinyltrifluoromethanesulfonamide with succinyl chloride

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详细

N -Sulfinyltrifluoromethanesulfonamide reacts with succinyl chloride to form 1-[(trifluoromethyl)sulfonyl]pyrrolidine-2,5-dione in high yield. The structure of the product was proved by X-ray diffraction analysis. The product is opened with ethanol under mild conditions selectively at the C-N bond to form (1 E )-4-ethoxy-4oxo- N -[(trifluoromethyl)sulfonyl]butanimidic acid.

作者简介

L. Tolstikova

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Email: tolstikova@irioch.irk.ru

I. Sterkhova

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Email: tolstikova@irioch.irk.ru

B. Shainyan

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Email: tolstikova@irioch.irk.ru

参考

  1. Davies T.Q., Willis M.C. Chem. Eur. J. 2021, 27, 8918-8927. doi: 10.1002/chem.202100321
  2. Shainyan B.A., Tolstikova L.L. Chem. Rev. 2013, 113, 699-733. doi: 10.1021/cr300220h
  3. Kresze G., Wucherpfennig W. Angew. Chem. Int. Ed. 1967, 6, 149-167. doi: 10.1002/anie.196701491
  4. Шаинян Б.А., Толстикова Л.Л., Бельских А.В. ЖОрХ. 2008, 44, 1136-1140.
  5. Tolstikova L.L., Shainyan B.A., Bel'skikh A.V. Russ.J. Org. Chem. 2008, 44, 1121-1125. doi: 10.1134/S1070428008080022
  6. Толстикова Л.Л., Шаинян Б.А., Стерхова И.В., Беловежец Л.А. ЖОрХ. 2020, 56, 83-87.
  7. Tolstikova L.L., Shainyan B.A., Sterkhova I.V., Belovezhets L.A. Russ. J. Org. Chem. 2020, 56, 63-67. doi: 10.1134/S107042802001011X
  8. Govindan K., Chen N.-Q., Chuang Y.-W., Lin W.-Y. Org. Lett. 2021, 23, 9419-9424. doi: 10.1021/acs.orglett.1c03541
  9. Sheldrick G.M. Acta Crystallogr., Sect. A. 2008, 64, 112-122. doi: 10.1107/S0108767307043930

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