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Reaction of N-sulfinyltrifluoromethanesulfonamide with succinyl chloride
- Authors: Tolstikova L.L1, Sterkhova I.V1, Shainyan B.A1
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Affiliations:
- A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
- Issue: Vol 59, No 3 (2023)
- Pages: 411-414
- Section: Articles
- URL: https://modernonco.orscience.ru/0514-7492/article/view/666377
- DOI: https://doi.org/10.31857/S0514749223030138
- EDN: https://elibrary.ru/TQOSNR
- ID: 666377
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Abstract
N -Sulfinyltrifluoromethanesulfonamide reacts with succinyl chloride to form 1-[(trifluoromethyl)sulfonyl]pyrrolidine-2,5-dione in high yield. The structure of the product was proved by X-ray diffraction analysis. The product is opened with ethanol under mild conditions selectively at the C-N bond to form (1 E )-4-ethoxy-4oxo- N -[(trifluoromethyl)sulfonyl]butanimidic acid.
About the authors
L. L Tolstikova
A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
Email: tolstikova@irioch.irk.ru
I. V Sterkhova
A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
Email: tolstikova@irioch.irk.ru
B. A Shainyan
A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
Email: tolstikova@irioch.irk.ru
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