Structure, phase composition and properties of amorphous soft magnetic Fe–Co–Si–B–P tapes

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription or Fee Access

Abstract

The analysis of structural and phase states, mechanical and magnetic properties of amorphous FeCoBSi and FeCoBSiP alloys obtained by spinning is performed. The distribution of the elemental composition is traced and the alloy stratification by silicon and boron is noted. It is shown that the experimentally determined values of saturation induction (1.7–1.8 T) and coercive force (18–20 A/m) are practically independent of changes in the composition of the tapes in the studied range of element content. The values of ultimate strength (~162 MPa) and elongation before failure (~0.23%) indicate low plasticity of the studied tapes. However, the value of the elastic modulus was high at 81.5 MPa.

Full Text

Restricted Access

About the authors

A. P. Semin

Siberian State Industrial University

Author for correspondence.
Email: syomin53@bk.com
Russian Federation, Novokuznetsk

V. E. Gromov

Siberian State Industrial University

Email: gromov@physics.sibsiu.ru
Russian Federation, Novokuznetsk

Yu. F. Ivanov

Institute of High-Current Electronics, Siberian Branch of the Russian Academy of Sciences

Email: yufi55@mail.ru
Russian Federation, Tomsk

S. V. Panin

Institute of Strength Physics and Materials Science

Email: paninsergey71@mail.ru
Russian Federation, Tomsk

P. S. Mogilnikov

Central Research Institute of Ferrous Metallurgy named after I.P. Bardin

Email: pavel_mog@mail.ru
Russian Federation, Moscow

I. Yu. Litovchenko

Institute of Strength Physics and Materials Science

Email: litovchenko@spti.tsu.ru
Russian Federation, Tomsk

I. D. Selivanov

Siberian State Industrial University

Email: ilyselivanov@mail.ru
Russian Federation, Novokuznetsk

References

  1. Yeh J.W., Chen S.K., Lin S.J., Gan J.Y., Chin T.S., Shun T.T., Tsau C.H., Chang S.Y. Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes // Adv. Eng. Mater. 2004. V. 6. P. 299–303.
  2. Cantor B., Chang I.T.H., Knight P., Vincent A.J.B. Microstructural development in equiatomic multicomponent alloys // Mater. Sc. Eng. A. 2004. V. 375. P. 213–218.
  3. Ye Y.F., Wang Q., Lu J., Liu C.T., Yang Y. High-entropy alloy: Challenges and prospects // Mater. Today. 2016. V. 19. P. 349–362.
  4. Miracle D.B., Senkov O.N. A critical review of high entropy alloys and related concepts // Acta Mater. 2017. V. 122. P. 448–511.
  5. Li Y.H., Zhang W., Qi T.L. New soft magnetic Fe25Co25Ni25(P, C, B)25 high entropy bulk metallic glasses with large supercooled liquid region // J. Alloy. Compd. 2017. V. 693. P. 25–31.
  6. Wang C., He A., Wang A., Pang J., Liang X., Li Q., Chang, C., Qiu K., Wang X. Effect of P on glass forming ability, magnetic properties and oxidation behavior of FeSiBP amorphous alloys // Intermetallics. 2017. V. 84. P. 142–147.
  7. Li P., Wang A., Liu C.T. A ductile high entropy alloy with attractive magnetic properties // J. Alloy. Compd. 2017. V. 694. P. 55–60.
  8. Zhang Y., Zuo T., Cheng Y., Liaw P.K. High-entropy alloys with high saturation magnetization, electrical resistivity, and malleability // Sci. Rep. 2013. V. 3. 1455.
  9. Karimi M.A., Shamanian M., Enayati M.H., Adamzadeh M., Imani M. Fabrication of a novel magnetic high entropy alloy with desirable mechanical properties by mechanical alloying and spark plasma sintering // J. Manul. Process. 2022. V. 84. P. 859–870.
  10. Li C., Li Q., Li M., Chang C., Li H., Dong Y., Sun Y. New ferromagnetic (Fe1/3Co1/3Ni1/3)80(P1/2B1/2)20 high entropy bulk metallic glass with superior magnetic and mechanical properties // J. Alloy. Compd. 2019. V. 791. P. 947–951.
  11. Vaidya M., Armugam S., Kashyap S., Murty B.S. Amorphization in equiatomic high entropy alloys // J. Non-Cryst. Solids. 2015. V. 413. P. 8–14.
  12. Shu F.Y., Liu S., Zhao H.Y., He W.X., Sui S.H., Zhang J., He P., Xu B.S. Structure and high-temperature property of amorphous composite coating synthesized by laser cladding FeCrCoNiSiB high-entropy alloy powder // J. Alloy. Compd. 2017. V. 731. P. 662–666.
  13. Кекало И.Б. Процессы структурной релаксации и физические свойства аморфных сплавов в 2 т. Т. 2.: монография. М.: Изд. дом МИСиС, 2016. 650 с.
  14. Семин А.П., Громов В.Е., Иванов Ю.Ф., Панин С.В., Колубаев Е.А., Литовченко И.Ю., Боровский С.В. Структура и свойства ленты магнитомягкого сплава Fe–Co–Ni–Si–B, изготовленной методом спиннингования // Физическая мезомеханика. 2024. Т. 27. № 5. С. 63–70.
  15. Gromov V.E., Potekaev A.I., Semin A.P., Kolubaev E.A., Mogilnikov P.S., Ivanov Yu.F., Panin S.V., Borovsky S.V., Litovchenko I.Yu., Kornienkov B.A. Structure and properties of a ribbon from FeCoNiSiB high-entropy alloy // Russian Physics J. 2024. V. 67. № 6. P. 756–764.
  16. Han Y., Kong F.L., Han F.F., Inoue A., Zhu S.L., Shalaan E., Al-Marzouki F. New Fe-based soft magnetic amorphous alloys with high saturation magnetization and good corrosion resistance for dust core application // Intermetallics. 2016. V. 76. P. 18–25. https://doi.org/10.1016/j.intermet.2016.05.011
  17. Roy R.K., Murugaiyan P., Panda A.K., Mitra A. Compositional optimization of high induction (>1.7 T) FeCo-based nanocomposite alloys with enhancement of thermo-physical and magnetic properties // Physica B: Condensed Matter. 2019. V. 566. P. 71–76. https://doi.org/10.1016/j.physb.2019.04.034
  18. Wang C., He A., Wang A., Pang J., Liang X., Li Q., Wang X. Effect of P on glass forming ability, magnetic properties and oxidation behavior of FeSiBP amorphous alloys // Intermetallics. 2017. V. 84. P. 142–147. https://doi.org/10.1016/j.intermet.2016.12.024
  19. Hou L., Yang W., Luo Q., Fan X., Liu H., Shen B. High Bs of FePBCCu nanocrystalline alloys with excellent soft-magnetic properties // J. Non-Crystalline Solids. 2020. V. 530. 119800. https://doi.org/10.1016/j.jnoncrysol.2019.119800

Supplementary files

Supplementary Files
Action
1. JATS XML
2. Fig. 1. DSC thermograms of samples (FeCo)82B13Si5 (a) and (FeCo)82B12Si4P2 (b).

Download (26KB)
3. Fig. 2. Electron microscopic image of the structure of the tape subjected to etching: a, b – alloy (FeCo)82B13Si5; c, d – alloy (FeCo)82B12Si4P2.

Download (40KB)
4. Fig. 3. Electron diffraction patterns of (FeCo)82B13Si5 (a) and (FeCo)82B12Si4P2 (b) alloy tapes.

Download (11KB)
5. Fig. 4. Electron microscopic image of the structure of the tape subjected to electrolytic thinning (a, b) and thinning by a flow of argon ions (c, d): a, c – bright fields; b, d – corresponding microelectron diffraction patterns.

Download (18KB)

Copyright (c) 2025 Russian Academy of Sciences