Triflamidation of Camphene in Nitrile Solutions

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Аннотация

The reaction of triflamide with camphene in nitrile solutions in the presence of NBS and NIS has been researched. The reactions in isobutyronitrile solution give of various products: dibromide, camphenol, bromamidation product and corresponding amidines. In the reaction in benzonitrile with NBS, two isomeric benzamidines were obtained and isolated. One of them is the product of rearrangement of the camphene framework during the reaction, while in the second one the original substrate structure is retained. When using NIS as an oxidizing agent in the same solvent, a similar mixture of isomers having an iodine atom was obtained.

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Авторлар туралы

M. Sobyanina

Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: ganin@irioch.irk.ru
ORCID iD: 0000-0002-0361-0897
Ресей, Irkutsk

I. Garagan

Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: ganin@irioch.irk.ru
ORCID iD: 0000-0003-3024-798X
Ресей, Irkutsk

A. Ganin

Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: ganin@irioch.irk.ru
ORCID iD: 0000-0003-1626-795X
Ресей, Irkutsk

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