CYCLOBIS(PARAQUAT-P-PHENYLENE) - MEDIATED ELECTROSYNTHESIS OF SILVER NANOPARTICLES

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Silver nanoparticles (Ag-NP) were obtained in MeCN/0.05 M Bu4NPF6 medium by сyclobis(paraquat-p-phenylene) (CBPQT4+) – mediated reduction of the silver ions generated by anodic oxidation of metallic silver during the electrolysis in an undivided cell. Due to multipoint donor-acceptor interaction CBPQT4+ binds the resulting electron-donor Ag-NP to each other, which leads to their enlargement, aggregation and adsorption. This property of the macrocycle allows to call it a “molecular glue” for NP-Ag. In the absence of stabilizers, aggregated polydisperse Ag-NP of indefinite shape are formed with sizes ranging from 20 to 500 nm. Electrosynthesis in the presence of a stabilizer, polyvinylpyrrolidone (PVP), also leads to the formation of aggregated smaller metal particles of 55 ± 26 nm, which have, in addition to the quasi-spherical shape, the shape of a flat triangle and hexagon. Ag-NP stabilized by PVP are partially bound on the surface of nanocellulose (NC). In the presence of NC, larger Ag-NP with an average size of 97 ± 29 nm are formed, the main shape of which is quasi-spherical; cubic, tetrahedral, and rod-shaped Ag-NP are also formed; the formation of Ag-NP with a flat structure is excluded. The catalytic activity of the obtained particles in the reduction of p-nitrophenol with sodium borohydride is extremely low due to the large size, aggregation, and coating of the NP-Ag surface with the stabilizer PVP and marcocycle. 

作者简介

G. Nasretdinova

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: nasybullina@iopc.ru
Arbuzov St. 8, Kazan, 420088 Russia

R. Fazleeva

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: yanilkin@iopc.ru
Arbuzov St. 8, Kazan, 420088 Russia

A. Yanilkin

Dukhov Research Institute of Automatics (VNIIA)

Email: yanilkin@iopc.ru
Syshevskaya str. 22, Moscow, 127030 Russia

A. Gubaidullin

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: yanilkin@iopc.ru
Arbuzov St. 8, Kazan, 420088 Russia.

E. Siraeva

Interdisciplinary Center “Analytical Microscopy”, Kazan Federal University

Email: yanilkin@iopc.ru
Kremlyovskaya Str. 18, Kazan, 420018 Russia

E. Mansurova

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: yanilkin@iopc.ru
Arbuzov St. 8, Kazan, 420088 Russia

A. Ziganshina

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: yanilkin@iopc.ru
Arbuzov St. 8, Kazan, 420088 Russia

V. Yanilkin

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: yanilkin@iopc.ru
Arbuzov St. 8, Kazan, 420088 Russia

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版权所有 © Г.Р. Насретдинова, Р.Р. Фазлеева, А.В. Янилкин, А.Т. Губайдуллин, Э.Т. Сираева, Э.Э. Мансурова, А.Ю. Зиганшина, В.В. Янилкин, 2023