Heterometallic Complex of Europium(III) Trifluoroacetate with Bis(diphenylphosphoryl)ferrocene (DPPFO2): Synthesis, Structure and Thermal Stability

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A new bimetallic complex [Eu2(OOCCF3)6(H2O)2(dppfO2)2] (I) was obtained by the reaction of aqueous europium(III) trifluoroacetate with bis(diphenylphosphoryl)ferrocene (DppfO2) in a solvent mixture of tetrahydrofuran-benzene (1: 1), and characterized by X-ray diffraction (CCDC No. 2425374), IR spectroscopy, and elemental analysis. According to the X-ray analysis data, compound I is a molecular complex in which two europium atoms are connected by bridging water molecules and trifluoroacetate anions, and terminal DppfO2 molecules are coordinated chelately. According to the STA data, the complex is thermally stable up to 200°C, its decomposition is accompanied by an exothermic effect at 285°C associated with the desorption of four trifluoroacetic acid molecules.

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作者简介

M. Uvarova

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: yak_marin@mail.ru
俄罗斯联邦, Moscow

M. Shmelev

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: yak_marin@mail.ru
俄罗斯联邦, Moscow

V. Eliseenkova

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; D. I. Mendeleev Russian University of Chemical Technology

Email: yak_marin@mail.ru
俄罗斯联邦, Moscow; Moscow

I. Lutsenko

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: yak_marin@mail.ru
俄罗斯联邦, Moscow

I. Eremenko

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: yak_marin@mail.ru
俄罗斯联邦, Moscow

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2. Scheme 1. Coordination capabilities of DppfO₂.

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3. Fig. 1. Structure of complex I. Hydrogen atoms and solvate molecules are not shown.

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4. Fig. 2. Coordination polyhedra of europium ions in the structure of complex I.

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5. Fig. 3. TG (blue) and DSC (red) curves for complex I (a); micromorphology photographs (100 μm; 10 μm) (b) and energy-dispersive spectrum of residue I (c).

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