Флуоресцентные наноматериалы из нанокристаллической целлюлозы

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Abstract

Флуоресцирующие наносистемы, содержащие углеродные квантовые точки (УКТ), получены одностадийным гидротермальным методом с использованием двух типов нанокристаллической целлюлозы (НКЦ): частиц с составом поверхности, близким к нативной целлюлозе (Н-НКЦ), и частиц с сульфатированной поверхностью (С-НКЦ). Наносистемы были охарактеризованы с помощью ультрафиолетовой спектроскопии, инфракрасной спектроскопии с преобразованием Фурье, анализа динамического светорассеяния и флуоресцентной микроскопии. ζ-Потенциал золей составляет от –9.4 до –22.4 мВ для УКТ/Н-НКЦ и –18.3 мВ для УКТ/С-НКЦ. Золи углеродных наночастиц имеют ярко-синее свечение при воздействии ультрафиолетового излучения и необычную флуоресценцию, не зависящую от возбуждения, с квантовым выходом излучения 8.70% для УКТ/Н-НКЦ и 0.84% для УКТ/С-НКЦ. Полученные наноматериалы проявляют высокую антирадикальную активность в тесте с 2,2-дифенил-1-пикрилгидразилом.

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Анна Геннадиевна Белых

Институт химии ФИЦ Коми научного центра Уральского отделения РАН

Author for correspondence.
Email: anna407@rambler.ru
ORCID iD: 0009-0001-6607-0621

к.т.н.

Russian Federation, 167000, г. Сыктывкар, ул. Первомайская, д. 48

Юлия Ивановна Друзь

Институт химии ФИЦ Коми научного центра Уральского отделения РАН

Email: anna407@rambler.ru
ORCID iD: 0000-0002-0119-5503
Russian Federation, 167000, г. Сыктывкар, ул. Первомайская, д. 48

Василий Игоревич Михайлов

Институт химии ФИЦ Коми научного центра Уральского отделения РАН

Email: anna407@rambler.ru
ORCID iD: 0000-0003-1544-6593

к.х.н.

Russian Federation, 167000, г. Сыктывкар, ул. Первомайская, д. 48

Петр Александрович Ситников

Институт химии ФИЦ Коми научного центра Уральского отделения РАН

Email: anna407@rambler.ru
ORCID iD: 0000-0002-9937-9801

к.х.н.

Russian Federation, 167000, г. Сыктывкар, ул. Первомайская, д. 48

Михаил Анатольевич Торлопов

Институт химии ФИЦ Коми научного центра Уральского отделения РАН

Email: anna407@rambler.ru
ORCID iD: 0000-0002-0991-906X

к.х.н.

Russian Federation, 167000, г. Сыктывкар, ул. Первомайская, д. 48

Оксана Георгиевна Шевченко

Институт биологии ФИЦ Коми научного центра Уральского отделения РАН

Email: anna407@rambler.ru
ORCID iD: 0000-0001-5331-3201

к.б.н.

Russian Federation, 167982, г. Сыктывкар, ГСП-2, ул. Коммунистическая, д. 28

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Supplementary files

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2. Fig. 1. Micrograph of native nanocrystalline cellulose.

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3. Fig. 2. Fourier transform IR spectra. 1 — native nanocellulose, 2 — carbon dots from native nanocellulose, 3 — carbon dots from sulfated nanocellulose, 4 — carbon dots from citric acid.

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4. Fig. 3. Absorption spectra of carbon dots obtained from: 1 - citric acid, 2 - sulfated nanocellulose, 3 - native nanocellulose.

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5. Fig. 4. Fluorescence spectra of carbon dots obtained from: a — citric acid at excitation wavelengths (nm): 1 — 300, 2 — 360, 3 — 370, 4 — 390, 5 — 410, 6 — 430, 7 — 450; b — native cellulose (hydrothermal method) at excitation wavelengths (nm): 1 — 310, 2 — 330, 3 — 350, 4 — 360, 5 — 370, 6 — 390; c — sulfated nanocellulose (hydrothermal method) at excitation wavelengths (nm): 1 — 310, 2 — 330, 3 — 350, 4 — 360, 5 — 370, 6 — 390; g — native cellulose (microwave method) at excitation wavelengths (nm): 1 — 300, 2 — 310, 3 — 330, 4 — 350, 5 — 360, 6 — 370, 7 — 390, 8 — 410, 9 — 430.

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6. Fig. 5. Comparative evaluation of the antiradical activity of carbon dots from nanocellulose at a concentration of 3.6–36 mg l–1 in a test with 2,2-diphenyl-1-picrylhydrazyl. UKT/S-NCC — carbon quantum dots from sulfated nanocellulose, UKT/N-NCC — carbon quantum dots from native nanocellulose.

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