Chloropentaammine- and Tris(ethylenediamine)cobalt(III) Oxalatocuprate(ii): Synthesis, Crystal Structure, Thermal Properties

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详细

This work is devoted to the synthesis and study of the thermal properties of new double complex salts [Co(NH3)5Cl][Cu(H2O)(C2O4)2] and [Co(en)3]2[Cu(H2O)(C2O4)2]2[Cu(H2O)2(C2O4)2] · 10H2O (en — ethylenediamine). The compounds were characterized by a series of physico-chemical analytical methods (PXRD, SCXRD, IR spectroscopy, elemental analysis). Thermal analysis and powder X-ray diffraction data showed that metastable CoxCu1–x solid solutions with high mutual solubility of metals are formed during the decomposition of complex salts. This work is one of the first examples of the formation of metastable solid solutions in the Co–Cu system.

作者简介

V. Lagunova

Nikolaev Institute of Inorganic Chemistry SB RAS

Email: varvara@niic.nsc.ru
Novosibirsk, 630090 Russia

E. Filatov

Nikolaev Institute of Inorganic Chemistry SB RAS

Email: varvara@niic.nsc.ru
Novosibirsk, 630090 Russia

P. Plyusnin

Nikolaev Institute of Inorganic Chemistry SB RAS

Email: varvara@niic.nsc.ru
Novosibirsk, 630090 Russia

N. Kuratieva

Nikolaev Institute of Inorganic Chemistry SB RAS

Email: varvara@niic.nsc.ru
Novosibirsk, 630090 Russia

S. Korenev

Nikolaev Institute of Inorganic Chemistry SB RAS

编辑信件的主要联系方式.
Email: varvara@niic.nsc.ru
Novosibirsk, 630090 Russia

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