Growth and Some Properties of Mixed Crystals of Non-Isostructural Series of Nickel and Cobalt Sulphates Hexahydrates

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Acesso é pago ou somente para assinantes

Resumo

The dependence of the solubility of NixCo1–xSO4·6H2O (x = 0–1) on the composition of the solution at a temperature of 45°C was obtained. It has been established that an increase in temperature leads to a shift in the point of non-invariant equilibrium of the tetragonal and monoclinic phases towards a higher concentration of cobalt in solution. A thermogravimetric study has shown that as the Co content in the crystal increases, its thermal stability decreases. The spectral characteristics of crystals of different compositions have shown that the crystal can be used as a UV filter. The habitus of a NixCo1–xSO4·6H2O monoclinic crystal obtained from a solution of the composition NiSO4 : CoSO4 = 50 : 50 wt. % has been determined.

Sobre autores

E. Rudneva

Shubnikov Institute of Crystallography of the Kurchatov Complex Crystallography and Photonics of the NRC “Kurchatov Institute”

Email: rudneva.e@crys.ras.ru
Moscow, 119333, Russia

V. Komornikov

Shubnikov Institute of Crystallography of the Kurchatov Complex Crystallography and Photonics of the NRC “Kurchatov Institute”

Moscow, 119333, Russia

I. Ryabov

National University of Science and Technology “MISIS”

Moscow, 119049, Russia

M. Lyasnikova

Shubnikov Institute of Crystallography of the Kurchatov Complex Crystallography and Photonics of the NRC “Kurchatov Institute”

Moscow, 119333, Russia

V. Manomenova

Shubnikov Institute of Crystallography of the Kurchatov Complex Crystallography and Photonics of the NRC “Kurchatov Institute”

Moscow, 119333, Russia

A. Voloshin

Shubnikov Institute of Crystallography of the Kurchatov Complex Crystallography and Photonics of the NRC “Kurchatov Institute”; National University of Science and Technology “MISIS”; Mendeleev University of Chemical Technology of Russia

Moscow, 119333, Russia; Moscow, 119049, Russia; Moscow, 125047, Russia

Bibliografia

  1. Белов А.А., Егоров В.В., Калинин А.П. и др. // Современные проблемы дистанционного зондирования Земли из космоса. 2010. Т. 7. № 2. С. 233.
  2. Волошин А.Э., Руднева Е.Б., Маноменова В.Л. и др. Патент РФ на изобретение № 2417388. 2006.
  3. Genbo S., Youping H., Zhengdong L. China Patent № 99108240. 2000.
  4. Genbo S., Xinxin Z., Youping H. China Patent № 1407143. 2002.
  5. Singh N., Partlow W., Strauch S. et al. US Patent № 5788765. 1998.
  6. Livneh S., Selin S., Zwieback I., Ruderman W. US Patent № 6452189. 2002.
  7. Маноменова В.Л., Руднева Е.Б., Волошин А.Э. и др.// Кристаллография. 2005. Т. 50. С. 937.
  8. Youping H., Genbo S., Xianchun Y. et al. // J. Cryst. Growth. 1996. V. 169. P. 193. https://doi.org/10.1016/0022-0248(96)00310-7
  9. Genbo S., Youping H., Zhengdong L. et al. // J. Cryst. Growth. 2000. V. 213. P. 99. http://doi.org/10.1016/S0022-0248(00)00304-3
  10. Genbo S., Zhuang X., Youping H.et al. // J. Phys. D. 2002. V. 35. P. 2652. https://doi.org/10.1088/0022-3727/35/20/327
  11. Youping H., Jianrong C., Genbo S. et al. // J. Cryst. Growth. 2001. V. 233. P. 809. https://doi.org/10.1016/S0022-0248(01)01564-0
  12. Дятлова Н.А., Маноменова В.Л., Руднева Е.Б. и др. // Кристаллография. 2013. Т. 58. С. 737. https://doi.org/10.7868/S0023476113040097
  13. Zhokhov A.A., Masalov V.M., Rudneva E.B. et al. // Mater. Res. Express. 2020. V. 7. 016202. https://doi.org/10.1088/2053-1591/ab5fa4
  14. Voloshin A., Rudneva E., Manomenova V. et al. // Crystals. 2019. V. 9. № 8. 390. https://doi.org/10.3390/cryst9080390
  15. Genbo S., Xinxin Z., Youping H. et al. // Cryst. Res. Technol. 2003. V. 38. P. 1087. https://doi.org/10.1002/crat.200310141
  16. Karvar S., Rezagholipour Dizaji H. // Bulg. Chem. Commun. 2017. V. 49 P. 608.
  17. Voloshin A.E., Manomenova V.L., Rudneva E.B. et al. // J. Cryst. Growth. 2018. V. 500. P. 98. https://doi.org/10.1016/j.jcrysgro.2018.08.018
  18. Komornikov V.A., Sorokina N.I., Vasilyeva N.A. et al. // J. Phys. Chem. Solids. 2024. V. 185. 111706. https://doi.org/10.1016/j.jpcs.2023.111706
  19. Stadnicka K., Glazer A., Koralewski M. // J. Acta Cryst. B. 1987. V. 43. P. 319. https://doi.org/10.1107/S0108768187097787
  20. Gerkin R.E., Reppart W.J. // Acta Cryst. C. 1988. V. 44. P. 1486. https://doi.org/10.1107/S0108270188004238
  21. Tiller W.A., Jackson K.A., Rutter J.W., Chalmers B. // Acta Metall. 1953. V. 1. P. 428. https://doi.org/10.1016/0001-6160(53)90126-6

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML
Baixar

Declaração de direitos autorais © Russian Academy of Sciences, 2025