Synthesis and structural features of Co(II) compounds with 3-arylidene-1-pyrroline derivatives and monocarboxylic acids anions

Yu. K. Voronina; Воронина Ю. К.; O. V. Zvereva; Зверева О. В.; M. A. Shmelev; Шмелев М. А.; E. N. Zorina-Tikhonova; Зорина-Тихонова Е. Н.; A. V. Rogachev; Рогачев А. В.; A. A. Sidorov; Сидоров А. А.; I. L. Eremenko; Еременко И. Л.

doi:10.31857/S0132344X25050071

Synthesis and structural features of Co(II) compounds with 3-arylidene-1-pyrroline derivatives and monocarboxylic acids anions

作者: Voronina Y.K.¹, Zvereva O.V.¹^,2, Shmelev M.A.¹, Zorina-Tikhonova E.N.¹, Rogachev A.V.³, Sidorov A.A.¹, Eremenko I.L.¹
隶属关系:
1. N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
2. A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
3. MIREA — Russian Technological University
期: 卷 51, 编号 5 (2025)
页面: 343-352
栏目: Articles
URL: https://modernonco.orscience.ru/0132-344X/article/view/685417
DOI: https://doi.org/10.31857/S0132344X25050071
EDN: https://elibrary.ru/KVJOUQ
ID: 685417

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A series of acetate and trifluoroacetate compounds of cobalt(II) with derivatives of 3-arylidene-1-pyrrolines (X-L; X = Cl, OH) as N-donor ligands was synthesized. Varying the synthesis and crystallization conditions made it possible to obtain coordination compounds of various compositions and structures: a tetranuclear complex based on a cubane fragment {Co₄(OH)₄}^4– — [Co₄(OH)₄(Cl–L)₄(OAc)₄] (I), a 1D-polymer complex [Co(H₂O)(Cl–L)₂(CF₃COO)_1.167(OAc)_0.833]_n (II) or a molecular complex [Co(OH–L)₂(OAc)₂] (III). The synthesized compounds were characterized by X-ray diffraction, IR spectroscopy and CHN analysis. The structure and crystal packing of the obtained complexes were analyzed in detail, the main structure-forming non-covalent interactions in crystals were identified.

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cobalt, 3-arylidene-1-pyrrolines, X-ray structural analysis, non-covalent interactions

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2. Fig. 1. Structure of the molecule (a) and fragment of the crystal packing (b) of compound I.

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3. Fig. 2. Structure of the monomer fragment (a), fragment of the polymer chain (b) and fragment of the crystal packing (c) of coordination polymer II.